Catalyst displacement assay: a supramolecular approach for the design of smart latent catalysts for pollutant monitoring and removal† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c6sc05584b Click here for additional data file.

Catalyst displacement assay: a supramolecular approach for the design of smart latent catalysts for pollutant monitoring and removal.

Latent catalysts can be tuned to function smartly by assigning a sensing threshold using the displacement approach for targeted analytes. Three cyano-bridged bimetallic complexes were synthesized as "smart" latent catalysts through the supramolecular assembly of different metallic donors [FeII(CN)6]4-, [FeII(tBubpy)(CN)4]2-, and FeII(tBubpy)2(CN)2 with a metallic acceptor [CuII(dien)]2+. The in...

Stretchable supramolecular hydrogels with triple shape memory effect† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c6sc02354a Click here for additional data file. Click here for additional data file. Click here for additional data file. Click here for additional data file.

Electrophilic bis-fluorophosphonium dications: Lewis acid catalysts from diphosphines† †Electronic supplementary information (ESI) available: Preparative, spectroscopic and analytical details for the experiments described herein. CCDC 1041558–1041565. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5sc00051c Click here for additional data file. Click here for additional data file.

A rational pre-catalyst design for bis-phosphine mono-oxide palladium catalyzed reactions† †Electronic supplementary information (ESI) available: Detailed experimental procedures and characterization data for all new compounds. CCDC 1512973–1512975. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c6sc05472b Click here for additional data file. Click here for additional data file.

Dynamic propeller conformation for the unprecedentedly high degree of chiral amplification of supramolecular helices† †Electronic supplementary information (ESI) available: Synthesis, analytical data and Fig. S1–S34. See DOI: 10.1039/c6sc02814d Click here for additional data file.